Sarkar, S. K. ; Palit, D. K. ; Rama Rao, K. V. S. ; Mittal, J. P. (1986) Real-time observation of: CF2 formation in the infrared multiple-photon dissociation of fluoroform-d Chemical Physics Letters, 131 (4-5). pp. 303-309. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(86)87155-X
Abstract
CF2 radicals are directly detected by transient absorption at 249 nm in the TEA CO2 laser-induced decomposition of CDF3. Vibrationally hot :CF2 radicals, Tv≈725 K, are produced in a 4-5 µs time scale. Second-order decay of :CF2 radicals is also observed, yielding the dimerisation rate constant K2 = 4.2 × 107 M−1 s−1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 89174 |
| Deposited On: | 30 Mar 2012 10:04 |
| Last Modified: | 23 Jun 2012 11:56 |
Repository Staff Only: item control page
