Chandrasekhar, Vadapalli ; Singh , Puja (2009) A pentahydrated diorganotin cation. Cocrystallization of [{n-Bu2Sn(H2O)5}][CF3SO3]2 and [{n-Bu2Sn(BPDO-II)2(H2O)2}][CF3SO3]2 Organometallics, 28 (17). pp. 4974-4978. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om9004803
Related URL: http://dx.doi.org/10.1021/om9004803
Abstract
A 1:2:1 reaction of [n-Bu2SnO]n, trifluoromethanesulfonic acid, and 4,4'-bipyridine N,N-dioxide (BPDO-II) afforded a cocrystal (1·H2O) of the unprecedented pentahydrated diorganotin cation [{n-Bu2Sn(H2O)5}][CF3SO3]2 (1A) and its coordination product [{n-Bu2Sn(BPDO-II)2(H2O)2}][CF3SO3]2 (1B). A variation in crystallization conditions led to the isolation of a coordination polymer, [{n-Bu2Sn(μ -BPDO-II)(H2O)2}{CF3SO3}2]n (2).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8911 |
| Deposited On: | 28 Oct 2010 10:35 |
| Last Modified: | 28 Oct 2010 10:35 |
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