Chandrasekhar, Vadapalli ; Singh, Puja (2008) Trapping a discrete [R2Sn(μ-OH)SnR2] motif. Synthesis and structural characterization of [{(Phen)(NO3)Me2Sn(μ -OH)SnMe2(NO3)(Phen)}{NO3}] (Phen = 1,10-Phenanthroline) Organometallics, 27 (16). pp. 4083-4087. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om800359b
Related URL: http://dx.doi.org/10.1021/om800359b
Abstract
The reaction of Me2SnCl2 with 2 equiv of silver nitrate in methanol followed by treatment with 2 equiv of water and 1 equiv of 4,4'-bipyridine in presence of 1,10-phenanthroline afforded the hydrolyzed product [(NO3)(Phen)Me2Sn(μ -OH)SnMe2(Phen)(NO3)]+[NO3]-(4), containing a [R2Sn(μ -OH)SnR2] unit where two diorganotin units are bridged by an unsupported hydroxide ligand.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8895 |
| Deposited On: | 28 Oct 2010 09:05 |
| Last Modified: | 28 Oct 2010 09:05 |
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