Chandrasekhar, Vadapalli ; Krishnan, Venkatasubbaiah ; Steiner, Alexander ; Bickley, Jamie F. (2003) Cyclotriphosphazene hydrazides as efficient multisite coordinationlLigands. η 3-fac-non-geminal-N3Coordination of spiro-N3P3[O2C12H8][N(Me)NH2]4 (L) in L2CoCl3 and L2M(NO3)2 (M = Ni, Zn, Cd) Inorganic Chemistry, 43 (1). pp. 166-172. ISSN 0020-1669
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/ic034561d?prev...
Related URL: http://dx.doi.org/10.1021/ic034561d
Abstract
The cyclophosphazene tetrahydrazide spiro-N3P3[O2C12H8][N(Me)NH2]4 (L) functions as a multisite coordination ligand and affords L2CoCl3·2CH3OH (4), L2Ni(NO3)2·2CHCl3·2.5H2O (5), L2Zn(NO3)2·2CH3CN·2H2O (6), and L2Cd(NO3)2 (7). Each of the cyclophosphazene ligands that is involved in coordination to the metal functions as a non-geminal-N3 donor coordinating through one ring nitrogen atom and two non-geminal-NH2 nitrogen atoms. The coordination geometry around the metal ion in 4-6 is approximately octahedral while it is severely distorted in the case of 7.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8888 |
| Deposited On: | 28 Oct 2010 10:39 |
| Last Modified: | 28 Oct 2010 10:39 |
Repository Staff Only: item control page
