Kinetics and mechanism of hallogenative oligomerization of mesityl oxide by Chloramin-T. Evidence for a novel pathway in aqueous sulphuric acid

Vivekanandan, S. ; Venkatarao, K. ; Santappa, M. ; Sanmuganathan, S. P. (1978) Kinetics and mechanism of hallogenative oligomerization of mesityl oxide by Chloramin-T. Evidence for a novel pathway in aqueous sulphuric acid Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 16A . pp. 519-520. ISSN 0376-4710

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Abstract

The kinetics of the reaction between mesityl oxide and chloramine-T (CAT) in aqueous sulphuric acid in the presence of KHSO4 has been studied. The results indicate a radical chain mechanism to be operative which is quite novel in CAT kinetics.

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ID Code:88822
Deposited On:29 Mar 2012 14:20
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