Thanasekaran, P. ; Rajendran, T. ; Rajagopal, S. ; Srinivasan, C. ; Ramaraj, R. ; Ramamurthy, P. ; Venkatachalapathy, B. (1997) Marcus inverted region in the photoinduced electron transfer reactions of Ruthenium(II)-Polypyridine complexes with phenolate ions The Journal of Physical Chemistry A, 101 (44). pp. 8195-8199. ISSN 1089-5639
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp971746v
Related URL: http://dx.doi.org/10.1021/jp971746v
Abstract
Ruthenium(II)-polypyridyl complexes of similar size but with variable reduction potential undergo efficient photoinduced electron-transfer reactions with phenolate ions in aqueous medium. All these reactions are exergonic and are in accordance with the Marcus theory of electron transfer. At high negative Δ G° Marcus inverted region is observed in this bimolecular photoinduced charge separation reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 88779 |
| Deposited On: | 29 Mar 2012 15:11 |
| Last Modified: | 29 Mar 2012 15:11 |
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