Chandrasekhar, Vadapalli ; Singh, Puja (2008) First example of a hydrated monoorganotin cation: Synthesis and structure of [{PhSn(H2O)3(μ -OH)}2][{1,5-C10H6-(SO3)2}2] Organometallics, 28 (1). pp. 42-44. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om800972m
Related URL: http://dx.doi.org/10.1021/om800972m
Abstract
The reaction of Ph2SnO with naphthalene-1,5-disulfonic acid tetrahydrate affords, through a Sn-aryl bond cleavage process, the first example of a hydrated monoorganotin cation, [{PhSn(H2O)3(μ -OH)}2][{1,5-C10H6-(SO3)2}2]. The structural elucidation of the latter showed that it contained a tetracationic dinuclear unit where the two tin atoms are bridged by two hydroxide ligands and each tin is hydrated with three molecules of water. Intermolecular hydrogen-bonding interactions between the water molecules and the disulfonate anions result in a pillared three-dimensional network.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8875 |
| Deposited On: | 28 Oct 2010 10:41 |
| Last Modified: | 28 Oct 2010 10:41 |
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