Jeong, I.-K. ; Ahn, J. S. ; Kim, B. G. ; Yoon, S. ; Singh, Satendra Pal ; Pandey, Dhananjai (2011) Short- and medium-range structure of multiferroic Pb(Fe1/2Nb1/2)O3 studied using neutron total scattering analysis Physical Review B: Condensed Matter, 83 (6). 064108_1-064112_5. ISSN 0163-1829
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Official URL: http://prb.aps.org/abstract/PRB/v83/i6/e064108
Related URL: http://dx.doi.org/10.1103/PhysRevB.83.064108
Abstract
We performed neutron total scattering analysis on multiferroic Pb(Fe1/2Nb1/2)O3 (PFN) from 300 K to 75 K and present the evolution of short- and medium-range atomic structures across the antiferromagnetic transition, TN=143 K. Over the whole temperature range, off-center displacement of Fe/Nb ions was not significant and Fe/Nb-O bond-length distribution exhibits little temperature dependence. In contrast, Pb-O bond length showed a rather distinct distribution at high and low temperatures. Using a comparison between crystallographic modeling and total scattering pair distribution function analysis we propose that a displacement of the Pb ion against the Fe/Nb ions is an important low-temperature structural feature. In addition, we present evidence for a static broadening at T=150 K due to the antiferromagnetic ordering of B-site Fe ions. Overall, we found that Fe/Nb ions play a role in the multiferroic properties of PFN by influencing off-centering behavior of the Pb ion with decreasing temperature.
Item Type: | Article |
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Source: | Copyright of this article belongs to The American Physical Society. |
ID Code: | 88716 |
Deposited On: | 29 Mar 2012 15:16 |
Last Modified: | 29 Mar 2012 15:16 |
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