Ferroelectric and antiferrodistortive phase transition in the multiferroic (Bi0.8Ba0.2)(Fe0.8Ti0.2)O3: A high temperature neutron powder diffraction study

Singh, Anar ; Senyshyn, Anatoliy ; Fuess, Hartmut ; Pandey, Dhananjai (2011) Ferroelectric and antiferrodistortive phase transition in the multiferroic (Bi0.8Ba0.2)(Fe0.8Ti0.2)O3: A high temperature neutron powder diffraction study Journal of Applied Physics, 110 (2). 024111_1-024111_6. ISSN 0021-8979

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Official URL: http://jap.aip.org/resource/1/japiau/v110/i2/p0241...

Related URL: http://dx.doi.org/10.1063/1.3606500

Abstract

Presented here are the results of Rietveld analysis of powder neutron diffraction data, which reveal that both the ferroelectric and antiferrodistortive phase transitions occur together at T ~ 925 K during heating, leading to a change in crystal structure from room temperature rhombohedral phase in the R3c space group with tilted oxygen octahedra to the high temperature paraelectric and paraelastic cubic phase in Pm3̅m space group. The presence of superlattice peaks due to antiphase rotation of oxygen octahedra in the rhombohedral phase until the transition to the cubic phase precludes the possibility of an intermediate R3m space group, conjectured previously on the basis of an x-ray powder diffraction study. Discontinuous change in the unit-cell volume, tilt angle, and bond lengths at the transition temperature TC, and phase coexistence of R3c and Pm3̅m over 100 K range across TC, suggest that the transition is of first order. It is argued that the R3c to Pm3̅m phase transition is of trigger type involving simultaneous condensation of Γ4- and R4+ modes.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
Keywords:Antiferromagnetic Materials; Barium Compounds; Bismuth Compounds; Bond Lengths; Condensation; Crystal Structure; Ferroelectric Materials; Ferroelectric Transitions; Heat Treatment; High-temperature Effects; Magnetic Transitions; Multiferroics; Neutron Diffraction; Space Groups; Superlattices
ID Code:88714
Deposited On:29 Mar 2012 15:16
Last Modified:29 Mar 2012 15:17

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