Greener Ullmann-type coupling of aryl halides for preparing biaryls using reusable Pd/ZrO2 catalyst

Dumbre, Deepa K. ; Wakharkar, Radhika D. ; Choudhary, Vasant R. (2010) Greener Ullmann-type coupling of aryl halides for preparing biaryls using reusable Pd/ZrO2 catalyst Synthetic Communications:, 41 (2). pp. 164-169. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397910903531805

Abstract

Biaryls with excellent yields can be prepared by the Ullmann-type coupling of aryl halides in the presence of potassium carbonate (as a base) and dimethylformamide (as a solvent), at 140 ° C, using a reusable Pd (2.5 wt%)/ZrO2 catalyst. The product yield of 4-iodoanisole coupling is strongly influenced by the catalyst preparation method, solvent, and base.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
Keywords:Aryl Halides; Biaryls; Pd/Zro2; Ullmann Coupling Reaction
ID Code:88563
Deposited On:29 Mar 2012 15:18
Last Modified:29 Mar 2012 15:18

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