Choudhary, Vasant R. ; Samanta, Chanchal ; Jana, Prabhas (2005) A novel route for in-situ H2O2 genration from selective reduction of O2 by hydrazine using heterogeneous Pd catalysts in an aqueous medium Chemical Communications, 2005 (43). pp. 5399-5401. ISSN 1359-7345
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/2005...
Related URL: http://dx.doi.org/10.1039/B510543A
Abstract
Hydrogen peroxide in high yields can be generated with high efficiency at mild conditions (25 ° C and atmospheric pressure) with the formation of only environment-friendly by-products (N2 and H2O) by a reduction of O2 by hydrazine from its hydrate/salt with its complete conversion in a short reaction period (=0.5 h) using a easily separable supported Pd catalyst (Pd/Al2O3, Pd/Ga2O3 or Pd/C) in an acidic aqueous medium in the presence of bromide anions; the presence of both acid (protons) and bromide anions is essential for the selective reduction of O2 by hydrazine to H2O2 and in their absence, the reaction leads only to the formation of water.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 88534 |
| Deposited On: | 29 Mar 2012 04:38 |
| Last Modified: | 29 Mar 2012 04:38 |
Repository Staff Only: item control page
