Oscillations in oxidative coupling of methane to C2-hydrocarbon over La2O3-BaO-MgO catalyst

Choudhary, V. R. ; Chaudhari, S. T. ; Rajput, A. M. ; Rane, V. H. (1989) Oscillations in oxidative coupling of methane to C2-hydrocarbon over La2O3-BaO-MgO catalyst Journal of the Chemical Society, Chemical Communications, 10 . pp. 605-606. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1989...

Related URL: http://dx.doi.org/10.1039/C39890000605

Abstract

Periodic fluctuations in reaction temperature indicating nearly symmetrical oscillations in the partial oxidation of methane by oxygen to ethane and ethylene in high yields over an La2O3-BaO-MgO (La/Mg = 0.1; Ba/Mg = 0.05) catalyst at reactor temperatures above 550° C but below 700° C have been observed.

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