Bag, Nilkamal ; Choudhury, Suranjan Bhanja ; Lahiri, Goutam Kumar ; Chakravorty, Animesh (1990) A novel zwitterionic ortho-metallated ruthenium(II) phenolate Journal of the Chemical Society, Chemical Communications (22). pp. 1626-1627. ISSN 1472-7773
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...
Related URL: http://dx.doi.org/10.1039/C39900001626
Abstract
Decarbonylative metallation of the dialdehyde 2b by [Ru(PPh3)3Cl2] affords the unusual complex [Ru(MeL)(CO)(PPh3)2(Cl)]4 which has been characterised by X-ray crystallography and in which the RuIIP2C2ClO coordination unit bears a single net negative charge; the Ru(MeL)(3, R = Me) fragment incorporates a four-membered C,O-chelated phenolato function with a neighbouring monoprotonated azomethine moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 88440 |
| Deposited On: | 28 Mar 2012 08:57 |
| Last Modified: | 13 Jul 2012 13:40 |
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