Pramanik, Amitava ; Bag, Nilkamal ; Ray, Debashis ; Lahiri, Goutam Kumar ; Chakravorty, Animesh (1991) Differentiation of isomeric coordination geometries by metal valence: a structural study of its origin in [Os(EtSCS2)2(PPh3)2] z(z= 0 and 1+) Journal of the Chemical Society, Chemical Communications (3). pp. 139-141. ISSN 1472-7773
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1991...
Related URL: http://dx.doi.org/10.1039/C39910000139
Abstract
In the title complexes OsII and OsIII display strong preferences for cis- and trans-S4 P2 geometries respectively; structural parameters of the cis-OsII, trans-OsII and trans-OsIII isomers have revealed that back-bonding and steric crowding within the Os(PPh3)2 fragment are the primary controlling factors.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 88439 |
| Deposited On: | 28 Mar 2012 08:57 |
| Last Modified: | 13 Jul 2012 13:43 |
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