Cyclophosphazene-supported tetranuclear copper assembly containing 15 contiguous inorganic rings

Chandrasekhar, Vadapalli ; Andavan, Gurusamy Thangavelu Senthil ; Azhakar, Ramachandran ; Pandian, Balasubramanian Murugesa (2008) Cyclophosphazene-supported tetranuclear copper assembly containing 15 contiguous inorganic rings Inorganic Chemistry, 47 (6). pp. 1922-1924. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic702500n

Related URL: http://dx.doi.org/10.1021/ic702500n

Abstract

The cyclophosphazene hydrazide gem-N3P3Ph2[N(Me)NH2]4 was reacted with o-hydroxybenzaldehyde to afford the multisite coordination ligand gem-N3P3Ph2[N(Me)N=CHC6H4-2-OH]4 (LH4). The latter reacted with copper(II) salts to afford a novel tetranuclear copper assembly {N3P3Ph2[N(Me)N=CHC6H4-2-O]4Cu2}2, which contains, remarkably, 15 contiguous inorganic rings.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:8841
Deposited On:28 Oct 2010 07:41
Last Modified:28 Oct 2010 07:41

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