Samajdar, Susanta ; Ghatak, Anjan ; Banerjee, Shyamapada ; Ghosh, Subrata (2001) An unusual reaction course in Rh(I)-induced decarbonylation of γ,δ-unsaturated aldehyde. Total synthesis of (±)-iso-β-necrodol and (±)-β-necrodol Journal of the Indian Institute of Science, 81 . pp. 149-153. ISSN 0970-4140
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Official URL: http://journal.library.iisc.ernet.in/vol200102/pap...
Abstract
Decarbonylation of the γ,δ-unsaturated aldehydes (4 and 9), embodied in a sterically congested carbon network, with Wilkinson's catalyst followed a reaction course different from the normal decarbonylation or hydroacylation path. This investigation has led to the synthesis of iso-β-necrodol and the monoterpene β-necrodol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Indian Institute of Science (IISc). |
| Keywords: | Monoterpene; Decarbonylation; Wilkinson' Catalyst; β-necrodol |
| ID Code: | 88009 |
| Deposited On: | 26 Mar 2012 13:54 |
| Last Modified: | 26 Mar 2012 13:54 |
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