Sinha, Saikat ; Bhaumik, Tanurima ; Ghosh, Subrata (2005) An asymmetric route to the construction of the bicyclic framework of marine eicosanoids Bacillariolides ARKIVOC: Online Journal of Organic Chemistry, xi . pp. 24-31. ISSN 1424-6376
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Official URL: https://www.arkat-usa.org/get-file/20340/
Abstract
A stereoselective route to the synthesis of γ -lactone fused cyclopentenes, the core structure of the marine eicosanoids bacillariolides, is described. The key step involves ring closing metathesis of 1,-6-diene built from D-mannitol to construct the cyclopentene unit in enantiomerically pure form.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Arkat-USA, Inc.. |
| Keywords: | Asymmetric Synthesis; Eicosanoids; Butanolides; Olefin Metathesis |
| ID Code: | 88004 |
| Deposited On: | 26 Mar 2012 13:54 |
| Last Modified: | 26 Mar 2012 13:54 |
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