Mondal, Sujit ; Yadav, Ram Naresh ; Ghosh, Subrata (2011) Influence of diene substituent position on the stereochemical outcome in IMDA reaction of decatrienones. An asymmetric synthesis of C10- epi-dihydro-epi-deoxy arteannuin B Organic Letters, 13 (22). pp. 6078-6081. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol202562w
Related URL: http://dx.doi.org/10.1021/ol202562w
Abstract
An asymmetric synthesis of C10-epi-dihydro-epi-deoxy arteannuin B is reported employing an IMDA reaction of sugar embedded decatrienone. During this investigation it has been demonstrated that changing the position of the methyl group on the diene moiety changes the stereochemical outcome leading to access to either cis- or trans-decalin derivatives exclusively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 87994 |
| Deposited On: | 26 Mar 2012 13:56 |
| Last Modified: | 26 Mar 2012 13:56 |
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