Brown, Herbert C. ; Basavaiah, D. (1982) A general and stereospecific synthesis of cis alkenes via stepwise hydroboration: a simple synthesis of muscalure, the sex pheromone of house fly (Musca domestica) Journal of Organic Chemistry, 47 (19). pp. 3806-3808. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00140a055
Related URL: http://dx.doi.org/10.1021/jo00140a055
Abstract
Base-induced iodination of hte vnylborane intermediates. conveniently obtained via the hydroboration of 1-alkynes with alkylbromoboranes (RBHBr-SMe2), provides cis-disubstituted alkenes in good yields. Muscalure, the insect pheromone of the housefly (Musca domestica), has been repared in 59% yield.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 87579 |
| Deposited On: | 20 Mar 2012 14:26 |
| Last Modified: | 20 Mar 2012 14:26 |
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