Basavaiah, Deevi ; Sarma, Pakala K. S. ; Bhavani, Anagani K. D. (1994) Applications of the Baylis-Hillman reaction. 2: A simple stereoselective synthesis of (E)- and (Z)-trisubstituted alkenes Journal of the Chemical Society - Section D: Chemical Communication, 1994 (9). pp. 1091-1092. ISSN 0577-6171
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1994...
Related URL: http://dx.doi.org/10.1039/C39940001091
Abstract
Reaction of Grignard reagents with methyl 3-acetoxy-2-methylenealkanoates produces (2E)-2-substituted alk-2-enoates, whereas a similar reaction with 3-acetoxy-2-methylenealkanenitriles provides (2Z)-2-substituted alk-2-enenitriles in high (Z)-stereoselectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 87578 |
| Deposited On: | 20 Mar 2012 14:26 |
| Last Modified: | 20 Mar 2012 14:26 |
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