Kumar, Pradeep ; Pandey, Menaka ; Gupta, Priti ; Vasudeva Naidu, S. ; Dhavale, Dilip D. (2010) Enantio-and diastereocontrolled total synthesis of (+)-strictifolione European Journal of Organic Chemistry, 2010 (36). pp. 6993-7004. ISSN 1434-193X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...
Related URL: http://dx.doi.org/10.1002/ejoc.201001221
Abstract
A concise and practical enantioselective synthesis of (+)-strictifolione has been achieved in high diastereomeric excess using Jacobsen's hydrolytic kinetic resolution, proline-catalyzed sequential α-aminoxylation and Horner-Wadsworth-Emmons olefination of aldehyde and cross olefin/ring-closing metathesis as the key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Natural Products; Total Synthesis; Asymmetric Synthesis; Organocatalysis; Ring-closing Metathesis; Hydrolytic Kinetic Resolution; Lactones |
| ID Code: | 87227 |
| Deposited On: | 16 Mar 2012 06:14 |
| Last Modified: | 19 Mar 2012 11:32 |
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