Mandal, Sanat Kumar ; Nag, Kamalaksha (1984) Synthesis of phenoxo-bridged dicopper(II) complexes of N-(2-aminoalkyl)salicylaldimines and their use in the formation of monohalogeno-complexes and non-symmetrical quadridentate Schiff-base complexes Journal of the Chemical Society Dalton Transactions (12). pp. 2839-2841. ISSN 1472-7773
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1984...
Related URL: http://dx.doi.org/10.1039/DT9840002839
Abstract
Phenoxo-bridged dicopper(II) complexes, [Cu2L12][ClO4]2·2H2O, of N-(2-aminoethyl)salicylaldimine (HL1) and its analogues have been synthesised by a high dilution method. These compounds react with p-substituted o-acylphenols and 1,3-diketones to form non-symmetrical quadridentate Schiff-base complexes. The phenoxo-bridge in [Cu2L12][ClO4]2·2H2O can be split by strong nucleophiles, yielding the monomeric compounds [CuL1(X)](X = Cl, Br, I, N3, or NCS). Similar reactions occur with [Cu2L72][ClO4]2·2H2O, where HL7is the reduced version of HL1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 86981 |
| Deposited On: | 14 Mar 2012 07:31 |
| Last Modified: | 14 Mar 2012 07:31 |
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