Piperaceae alkaloids: Part III. Synthesis of N-isobutyl-11-(3,4-methylenedioxyphenyl)-undeca-2,4,6-trans, trans, trans-trienoic amide and N-isobutyl-11-(3,4-methylenedioxyphenyl)-undeca-2,8,10-trans, trans, trans-trienoic amide (piperstachine)

Viswanathan, Narayanan ; Balakrishnan, Venkatachalam ; Joshi, Balawant S. ; von Philipsborn, Wolfgang (1975) Piperaceae alkaloids: Part III. Synthesis of N-isobutyl-11-(3,4-methylenedioxyphenyl)-undeca-2,4,6-trans, trans, trans-trienoic amide and N-isobutyl-11-(3,4-methylenedioxyphenyl)-undeca-2,8,10-trans, trans, trans-trienoic amide (piperstachine) Helvetica Chimica Acta, 58 (7). pp. 2026-2035. ISSN 0018-019X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/hlca.19...

Related URL: http://dx.doi.org/10.1002/hlca.19750580717

Abstract

N-Isobutyl-11-(3, 4-methylenedioxyphenyl)-undeca-2,4,6-trans, trans, trans-trienoic amide (II) and N-isobutyl-11-(3,4-methylenedioxyphenyl)-undeca-2,8,10-trans, trans, trans-trienoic amide (III), two of the three possible structures of the alkaloid piperstachine, have been synthesized. Compound (III) has been found to be identical with piperstachine. The 1H- and 13C-NMR. spectra of the compound (II) are discussed.

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Deposited On:13 Mar 2012 14:51
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