Yadav, Veejendra K. ; Gupta, Archana ; Agarwal, Divya ; Srivastava, Sachin ; Yadava, Virendra S. (2005) 1-Substituted-tricyclo[2.1.0.02,5]pentan-3-ones. Revisiting the diastereoselectivity ARKIVOC: Online Journal of Organic Chemistry, 2005 (3). pp. 67-73. ISSN 1424-6376
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Official URL: http://www.arkat-usa.org/get-file/20045/
Abstract
The π-selectivity of 1-substituted tricyclo[2.1.0.02,5]pentan-3-one is not controlled by the electrostatic effects caused by the polarization of the σC1C5 bond as suggested recently. The observed selectivity could be explained by the application of the cation complexation approach.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Arkat-USA, Inc. |
| Keywords: | Tricyclo[2.1.0.02,5]pentan-3-one; Diastereoselectivity; Electrostatic Effects; Cation Complexation Approach |
| ID Code: | 86548 |
| Deposited On: | 12 Mar 2012 07:28 |
| Last Modified: | 12 Mar 2012 07:28 |
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