A comparison of the Cieplak model and the cation complexation model as applied to selected 2,3-disubstituted norbornan-7-ones

Yadav, Veejendra K. ; Balamurugan, Rengarajan (2001) A comparison of the Cieplak model and the cation complexation model as applied to selected 2,3-disubstituted norbornan-7-ones Journal of the Chemical Society, Perkin Transactions 2 (1). pp. 1-2. ISSN 1364-5471

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2001...

Related URL: http://dx.doi.org/10.1039/B008808K

Abstract

Compared with the Cieplak model, which is totally inadequate for predicting the p-selectivities of 1a-1c, the antiperiplanar effects in suitably cation-complexed species predict carbonyl pyramidalizations that lead to the observed selectivities.

Item Type:Article
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Deposited On:12 Mar 2012 07:28
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