Yadav, Veejendra K. ; Balamurugan, Rengarajan (2002) Synthesis of γ-methylene oxacycles and α- and β-alkylidene lactones via silicon-assisted ring opening of cyclopropyl carbinols Chemical Communications (5). pp. 514-515. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2002...
Related URL: http://dx.doi.org/10.1039/B111332C
Abstract
Cyclopropyl carbinols bearing a (tert-butyldiphenylsilyl)methyl substituent undergo silicon-assisted regioselective ring cleavage and the resulting β-silyl carbocation is intramolecularly trapped with hydroxy and ester functions to generate γ-methylene oxacycles and α- and β-alkylidene lactones without the cleavage of the silicon function.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 86540 |
| Deposited On: | 12 Mar 2012 07:28 |
| Last Modified: | 12 Mar 2012 07:28 |
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