Electric conductivity and relaxation in ZnF2-AlF3-PbF2-LiF glasses

Sural, M. ; Ghosh, A. (2000) Electric conductivity and relaxation in ZnF2-AlF3-PbF2-LiF glasses Solid State Ionics, 130 (3-4). pp. 259-266. ISSN 0167-2738

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0167-2738(00)00641-X

Abstract

The electric conductivity of ZnF2-AlF3-PbF2-LiF glasses has been studied in the frequency range 10 Hz-2 MHz and in the temperature range from 300 K to just below the glass transition temperature. The conductivity decreases with the increase in the LiF content in the composition, which results from the trapping of F- ions by Li+ ions. Small values of the stretching exponent β are observed for the present glasses. The value of the decoupling index decreases with an increase in LiF content, consistent with the composition dependence of the conductivity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Ionic Conductivity; Ionic Relaxation; Fluoride Glass
ID Code:86394
Deposited On:10 Mar 2012 06:53
Last Modified:10 Mar 2012 06:53

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