Das, P. ; Venkitachalam, T. ; Bersohn, Richard (1984) On the absence of I(2P½) as a product of the reactions of F atoms with HI, I2, and ICN Journal of Chemical Physics, 80 (10). 4859_1-4859_4. ISSN 0021-9606
Full text not available from this repository.
Official URL: http://jcp.aip.org/resource/1/jcpsa6/v80/i10/p4859...
Related URL: http://dx.doi.org/10.1063/1.446507
Abstract
It is shown by two photon laser induced fluorescence that virtually no I(2P½) atoms are products of the reactions of F atoms with HI, I2, and ICN. A simple electrostatic model is used to prove that the potential surface beginning at F∗(2P½)+RI and ending at RF+I∗(2P½) must have an intermediate maximum. Moreover, this surface must cross a surface leading to ground state I atoms at two points. It is concluded that the propensity to form I rather than I∗ atoms is not general but depends on specific properties of the potential surfaces.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| Keywords: | Fluorine; Iodine Compounds; Cyanides; Fluorescence; Chemical Reactions; Chemiluminescence |
| ID Code: | 86325 |
| Deposited On: | 09 Mar 2012 10:35 |
| Last Modified: | 09 Mar 2012 10:35 |
Repository Staff Only: item control page
