Direct asymmetric Aldol reaction catalyzed by nanocrystalline magnesium oxide

Choudary, B. M. ; Chakrapani, L. ; Ramani, T. ; Kumar, K. V. ; Kantam, M. L. (2006) Direct asymmetric Aldol reaction catalyzed by nanocrystalline magnesium oxide Tetrahedron, 62 (41). pp. 9571-9576. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2006.07.091

Abstract

Nanomaterials with their three-dimensional structure and defined size and shape are considered to be suitable candidates for proper alignment with prochiral substrates for unidirectional introduction of reacting species to induce an asymmetric centre. The reusable and suitably aligned nanocrystalline magnesium oxide catalyzed direct asymmetric aldol reaction afforded the chiral β-hydroxy carbonyl compounds in good yields and moderate ee's.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Direct Asymmetric Aldol Reaction; NAP-Mgo; Enantiomeric Excess; β-hydroxy Carbonyl Compounds
ID Code:86046
Deposited On:17 Mar 2012 13:17
Last Modified:17 Mar 2012 13:17

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