Choudary, Boyapati M. ; Durga Prasad, Annavajhula ; Swapna, Vinukonda ; Valli, Velaga L. K. ; Bhuma, Vedantam (1992) Chromium pillared clay catalysed allylic oxidation and oxidative deprotection of allyl ethers and amines: a simple and convenient procedure Tetrahedron, 48 (5). pp. 953-962. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)88197-7
Abstract
An efficient method for allylic oxidation of cyclic and acyclic alkenes to the corresponding α,β-unsaturated carbonyl compounds in good yields was described using catalytic amounts of chromia-pillared montmorillonite and equimolar quantities of tert-butyl hydroperoxide. This is also a convenient method for selective oxidative deprotection of allyl ethers and amines using same system. Incidentally this is the first heterogeneous system for the allylic oxidation as well as oxidative deprotection.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 86007 |
| Deposited On: | 07 Mar 2012 13:42 |
| Last Modified: | 07 Mar 2012 13:42 |
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