Molecular complexes of metallo tetraphenyl porphyrins with 2,4,5,7- tetranitro fluorenone

Abstract

The interactions of mesotetraphenyl porphyrin and its metallo derivatives with 2,4,5,7-tetra nitrofluorenone have been studied using spectroscopic methods. The association constants (K) for 1:1 complexes in Ch₂Cl₂Cl₂ follow the order Pd⁺²>Co⁺²> Cu⁺²>VO⁺²>Ni⁺²>Zn⁺². The values of K are accounted in terms of stereochemistry of MTPPs and the electronic configuration of the metal ions. The magnitude and direction of the proton NMR shifts of the acceptor and donor in the complexes and their ESR parameter furnish information as to the possible structures of these complexes in solution.