Kulkarni, Surendra U. ; Basavaiah, D. ; Brown, Herbert C. (1982) Iodine induced transfer of dialkylvinylboranes produced by the hydridation of dialkylhaloboranes in the presence of 1-alkynes. Generalization of the Zweifel cis- alkene synthesis Journal of Organometallic Chemistry, 225 (1). C1-C5. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)86837-0
Abstract
Dialkylvinylboranes, prepared conveniently via the hydridation of dialkylhaloboranes in the presence of terminal alkynes, react with iodine in the presence of a base at reduced temperatures to form the correspondingcis-disubstituted alkenes. This development greatly increases the generality of the elegant weifelcis-olefin synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 85805 |
| Deposited On: | 06 Mar 2012 06:50 |
| Last Modified: | 06 Mar 2012 06:50 |
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