DABCO catalyzed dimerization of α,β -unsaturated ketones and nitriles

Basavaiah, D. ; Gowriswari, V. V. L. ; Bharathi, T. K. (1987) DABCO catalyzed dimerization of α,β -unsaturated ketones and nitriles Tetrahedron Letters, 28 (39). pp. 4591-4592. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)96573-0

Abstract

α ,β -Unsaturated ketones dimerize in the presence of catalytic amount of 1,4-diazabicyclo[2.2.2]octane(DABCO) to produce the corresponding 2-methylene-1,5-diketones in good yields. Acrylonitrile provides the corresponding dimerized product.

Item Type:Article
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ID Code:85787
Deposited On:06 Mar 2012 07:04
Last Modified:06 Mar 2012 07:04

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