Balasubramanian, T. S. ; Shukla, A. K. (1993) Effect of metal-sulfide additives on charge/discharge reactions of the alkaline iron electrode Journal of Power Sources, 41 (1-2). pp. 99-105. ISSN 0378-7753
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0378-7753(93)85008-C
Abstract
The effect of FeS, PbS and Bi2S3 additives on the charge/discharge reactions of porous iron electrodes in alkaline media are examined by means of steady-state galvanostatic and potentiostatic polarization, as well as by gasometric methods. It is found that these additives do not affect the reaction kinetics on fully-charged iron electrodes, but retard the rapid onset of passivation. By contrast, a distinct effect of these additives is observed on the kinetics of the hydrogen-evolution reaction during electrode charging.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 84723 |
| Deposited On: | 27 Feb 2012 13:20 |
| Last Modified: | 27 Feb 2012 13:20 |
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