Gopalakrishnan, J. (1984) Preparative solid state chemistry: recent developments Proceedings of the Indian Academy of Sciences - Chemical Sciences, 93 (3). pp. 421-432. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/93/vol93con...
Related URL: http://dx.doi.org/10.1007/BF02840529
Abstract
A survey of recent developments in preparative solid state chemistry shows that, with a knowledge of structural chemistry and reactivity patterns of solids, it is possible to synthesize a variety of new solids possessing novel structures. A distinction is made between synthesis ofnew solids and synthesis of solids bynew methods. Three new routes to solid state synthesis are recognized: the precursor method, and topochemical methods involving redox and ion-exchange reactions. The low-temperature topochemical methods enable synthesis of metastable phases that are inaccessible by the high temperature route. Several illustrative examples of solid state synthesis from the recent literature are presented.
Item Type: | Article |
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Source: | Copyright of this article belongs to Indian Academy of Sciences. |
Keywords: | Preparative Solid State Chemistry; New Methods; New Solids |
ID Code: | 84368 |
Deposited On: | 25 Feb 2012 05:43 |
Last Modified: | 25 Feb 2012 05:43 |
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