Oxidative addition of dimethyl malonate to styrenes mediated by cerium(IV) ammonium nitrate: some novel observations

Nair, Vijay ; Mathew, Jessy ; Nair, Latha G. (1997) Oxidative addition of dimethyl malonate to styrenes mediated by cerium(IV) ammonium nitrate: some novel observations Synthetic Communications, 27 (17). pp. 3053-3064. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919708005011

Abstract

The oxidative addition of dimethyl malonate to ring substituted styrenes leads to the formation of substituted dimethyl (2-oxo-2-phenylethyl) malonate and methyl 2-oxo-5-phenyltetrahydrofuran-3-carboxylate along with small amounts of substituted dimethyl [2-(nitrooxy)-2-phenylethyl] malonate and dimethyl 2-methoxy-2-phenylethyl) malonate. A tentative mechanism which supports the formation of these products is also presented.

Item Type:Article
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Deposited On:24 Feb 2012 11:40
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