Carbon-heteroatom bond-forming reactions mediated by cerium(IV) ammonium nitrate: an overview

Nair, Vijay ; Panicker, Sreeletha B. ; Nair, Latha G. ; George, Tesmol G. ; Augustine, Anu (2003) Carbon-heteroatom bond-forming reactions mediated by cerium(IV) ammonium nitrate: an overview Synlett, 2003 (2). 0156-0165. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2003-36775

Abstract

As a powerful one-electron oxidant, cerium(IV) ammonium nitrate (CAN) is useful for a variety of oxidative transformations including carbon-carbon bond formation. Recent work has also demonstrated the usefulness of CAN in carbon-heteroatom bond-forming reactions. Particularly noteworthy is the effectiveness of CAN in building C-N, C-S, C-Se, C-Br, and C-I bonds. This account is aimed at creating awareness among organic chemists about such reactions with potential application in the synthesis of a variety of building blocks.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Cerium(IV) Ammonium Nitrate; Radical Reactions; Bond-forming Reactions; Heteroatoms; Oxidations
ID Code:84115
Deposited On:24 Feb 2012 06:07
Last Modified:24 Feb 2012 06:07

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