A stereoselective synthesis of spiro-dioxolanes via the multicomponent reaction of dicarbomethoxycarbene, aldehydes and 1,2- or 1,4-diones

Nair, Vijay ; Mathai, Sindhu ; Mathew, Smitha C. ; Rath, Nigam P. (2005) A stereoselective synthesis of spiro-dioxolanes via the multicomponent reaction of dicarbomethoxycarbene, aldehydes and 1,2- or 1,4-diones Tetrahedron, 61 (11). pp. 2849-2856. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2005.01.076

Abstract

The three component reaction of acyclic carbonyl ylides generated from dicarbomethoxycarbene and aldehydes with 1,2- and 1,4-diones is described. The reaction afforded the corresponding spiro-dioxolanes in good yields.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Dicarbomethoxycarbene; Carbonyl Ylide; Huisgen 1; 3-dipolar Cycloaddition; Spiro-dioxolane
ID Code:84100
Deposited On:24 Feb 2012 06:10
Last Modified:24 Feb 2012 06:10

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