Banerjee, Asoke K. ; Mukhopadhyay, Anup K. ; Mukherjee, Ranajit K. ; Chowdhury, Mihir (1979) 7F0-5D1 transition in Eu3+-hexakisantipyrene-triiodide single crystal. A magnetic dipole transition Chemical Physics Letters, 67 (2-3). pp. 418-419. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(79)85192-1
Abstract
The polarised absorption spectrum of Eu3+-hexakisantipyrene-triiodide (HAPI) at 77 K along with a Zeeman effect study is reported. The7F0→5D1 transition has been found to be magnetic dipole allowed. The g value of 1.48 ± 0.06 for the 5D1 state is in fair agreement with the g value of the free ion. This fact together with the absence of any vibronic band (unlike other HAPI crystals) is indicative of negligible covalent character of the Eu-O bond.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 8369 |
Deposited On: | 26 Oct 2010 11:37 |
Last Modified: | 04 Feb 2011 04:03 |
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