Jemmis, Eluvathingal D. ; Pavan Kumar, P. N. V. ; Sreenivas Kumar, N. R. (1987) Structure and bonding in (R2SiX)2 molecules (X = O, NH, CH2, or S; R = H) Journal of the Chemical Society Dalton Transactions, 1987 (1). pp. 271-273. ISSN 1472-7773
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1987...
Related URL: http://dx.doi.org/10.1039/DT9870000271
Abstract
Analysis of the structure and bonding in (R2SiX)2 molecules (X = O, NH, CH2, or S; R = H) by empirical, MNDO, and ab initio molecular orbital methods shows that: (a) the electronic structures of these systems are qualitatively similar, (b) short non- bonded 1,3-Si-Si distances are predominantly determined by the Si-X distance, and (c) the small antibonding Si-Si interactions increase with increasing Si-Si distance.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 83398 |
| Deposited On: | 20 Feb 2012 09:16 |
| Last Modified: | 20 Feb 2012 09:16 |
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