Howell, James A. S. ; Mathur, Pradeep (1979) A bridge opening selectivity in the adams-cotton mechanism: the preparation and fluxional behaviour of (η5-Cp)2Fe2(CO)2(CNBu-t)2 Journal of Organometallic Chemistry, 174 (3). pp. 335-341. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)85598-9
Abstract
The title molecule exists in solution as a mixture of (η5-Cp)2Fe2(μ-CO)2(CNBu-t)2 and (η5-Cp)2Fe2(μ-CO)(μ-CNBu-t)(CO)(CNBu-t) isomers. NMR studies show that interconversion by the Adams-Cotton mechanism proceeds by two different pathways having significantly different activation energies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83081 |
| Deposited On: | 16 Feb 2012 07:39 |
| Last Modified: | 16 Feb 2012 07:39 |
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