Mathur, Pradeep ; Chatterjee, Saurav ; Das, Atanu ; Mobin, Shaikh M. (2007) Photochemical route to unusual tri-tungsten ferrocenylacetylene cluster [W3{μ-η2,η2- (H)C≡CFc}2(CO)12] and a dimetallacyclodecatetraene [W2{μ-η2,η2,η2,η2- (Fc)C=C(H)C(H)=C(Fc)C(Fc)=C(H)C(H)=C(Fc)}(CO)6] Journal of Organometallic Chemistry, 692 (4). pp. 819-823. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2006.10.022
Abstract
Low temperature photoreaction between tungsten hexacarbonyl and ferrocenylacetylene yielded two unusual metal containing stable compounds, the tritungsten cluster, [W3(μ-η2,η2- (H)C≡CFc)2(CO)12] (1), and ditungsten-1,4,5,8-ferrocenylcyclodecatetraene, [W2{μ-μ2,η2,η2,η2-(Fc)C=C(H)C(H)=C(Fc)C(Fc)=C(H)C(H)=C(Fc)}(CO)6] (2). Both compounds were characterised by IR and 1H and 13C NMR spectroscopy and their molecular structures established by single crystal X-ray diffraction methods.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Tungsten Carbonyl Cluster; Dimetallacyclodecatetraene; Ferrocenylacetylene; Crystal Structures |
| ID Code: | 83072 |
| Deposited On: | 16 Feb 2012 07:54 |
| Last Modified: | 16 Feb 2012 07:54 |
Repository Staff Only: item control page
