Mathur, Pradeep ; Ghosh, Sundargopal ; Sarkar, Amitabha ; Rheingold, Arnold L. ; Guzei, Ilia A. (1998) An unusual cyclopentaannulation reaction: thermolysis of an α,β-unsaturated fischer carbene complex anchored on a Fe2(CO)6(μ-Se)2 core Organometallics, 17 (4). pp. 770-772. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om9708182
Related URL: http://dx.doi.org/10.1021/om9708182
Abstract
An unusual annulation of a Fischer carbene complex anchored on a Fe2(CO)6(μ-Se)2 core is examined. Thermolysis of Fe2(CO)6{μ-SeC(Ph)=C(Se)[(OEt)C=Cr(CO)5]} in THF yields an unusual annulated product, [Fe2(CO)6Se2{μ-(CO)3Cr(η5-C5H(CH2Ph)(Ph)(OEt))}], as characterized by IR and 1H, 13C, and 77Se NMR spectroscopies, and its structure has been established by single-crystal X-ray diffraction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 83066 |
| Deposited On: | 16 Feb 2012 07:53 |
| Last Modified: | 16 Feb 2012 07:53 |
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