Mathur, Pradeep ; Ghose, Sanjukta ; Munkir Hossain, Md. ; Vahrenkamp, Heinrich (1997) Synthesis and structural characterisation of a new μ2-Te bridged complex of molybdenum with oxo and imido ligands Journal of Organometallic Chemistry, 538 (1-2). pp. 185-188. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0022-328X(96)06903-3
Abstract
Reflux of a benzene solution of Cp2Mo2Fe2(CO)7Te2 and PhN3 in the presence of air afforded the new compound Cp2Mo2O2(μ-Te)(μ-NC6H5) in 33% yield. It was characterised by IR and 1H and 125Te NMR. spectroscopy. Crystallographic analysis established its structure. The structure can be described as consisting of a CpMo-MoCp unit, bridged by a μ-Te atom and an imido ligand. Also bonded to each Mo atom is a terminally bonded oxo group.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Molybdenum; Tellurium; Oxo; Imido; Azide; Dinuclear |
| ID Code: | 83063 |
| Deposited On: | 16 Feb 2012 07:52 |
| Last Modified: | 16 Feb 2012 07:52 |
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