Mathur, Pradeep ; Munkir Hossain, Md. ; Umbarkar, Shubhangi ; Satyanarayana, C. V. V. ; Puranik, Vedavati G. (1996) Propargyl alcohol derivatives of Fe2(CO)6(μ-EE') (E,E' = S, Se or Te): synthesis and spectroscopic characterization of (CO)6Fe2{μ-EC(H) = C(CH2OH)E'} (E = Se or Te; E' = S, Se or Te); crystal structure of (CO)5(PPh3)Fe2{μ-SeC(CH2OH) = C(H)Se} Journal of Organometallic Chemistry, 506 (1-2). pp. 313-319. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(95)05750-J
Abstract
The propargyl alcohol derivatives ((CO)6Fe2{μ-EC(H) = C(CH2OH)E'} (E = Se or Te; E' = S, Se or Te) were obtained from the room-temperature reaction of Fe2(CO)6(μ-EE') with propagyl alcohol and were characterized by IR and 1H, 13C, 77Se and 125Te NMR spectroscopy. The structure of PPh3-substituted derivative (CO)5(PPh3)Fe2{μ-SeC(CH2OH)=C(H)Se} was established by a single-crystal X-ray diffraction study.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iron; Selenium; Sulfur; Tellurium; Carbonyl; Propargyl Alcohol |
| ID Code: | 83054 |
| Deposited On: | 16 Feb 2012 04:20 |
| Last Modified: | 16 Feb 2012 04:20 |
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