Mathur, Pradeep ; Dash, Aswini K. ; Munkir Hossain, Md. ; Satyanarayana, C. V. V. (1995) Acetylenic derivatives of Fe2(CO)6(μ-Se2): synthesis and spectroscopic characterization of [(CO)6Fe2{μ-SeC(H)=C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)-C(H)}] Journal of Organometallic Chemistry, 493 (1-2). pp. 257-260. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(94)05350-K
Abstract
The new acetylenic derivatives [(CO)6Fe2{μ-SeC(H)-C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)-C(H)}] have been isolated from the room-temperature reaction of Fe2(CO)6(μ-Se2) with acetylene in methanol solvent containing sodium acetate. The products have been characterized by IR and 1H, 13C and 77Se NMR spectroscopy. The NMR spectroscopic features of the related phenylacetylene derivatives [(CO)6Fe2{μ-SeC(Ph)=C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(Ph)-C(H)}] are also reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iron; Selenium |
| ID Code: | 83051 |
| Deposited On: | 16 Feb 2012 04:19 |
| Last Modified: | 16 Feb 2012 04:19 |
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