Acetylenic derivatives of [Fe2(CO)6(μ-Se2)]: acetylenic bond reduction on a selenium-stabilised Fe2Pt mixed-metal complex

Mathur, Pradeep ; Hossain, Munkir ; Das, Kalyan ; Sinha, Umesh C. (1993) Acetylenic derivatives of [Fe2(CO)6(μ-Se2)]: acetylenic bond reduction on a selenium-stabilised Fe2Pt mixed-metal complex Journal of the Chemical Society, Chemical Communications (1). pp. 46-48. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1993...

Related URL: http://dx.doi.org/10.1039/C39930000046

Abstract

Stepwise addition of phenylacetylene and Pt(PPh3)2 across the Se-Se bond of [Fe2(CO)6(μ-Se2)] can be carried out at room temperature; X-ray analysis demonstrates the acetylenic carbon-carbon bond reduction in the mixed-metal complex [(CO)6Fe2Pt(PPh3)2{μ-SeC(Ph)C(H)Se}].

Item Type:Article
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