Mathur, Pradeep ; Dayal Reddy, V. (1990) Reduction of (μ2-Te2)Fe2(CO)6 and reaction of the dianion formed with metal dihalides, L2MCl2, (L = PPh3, M = Pt, Pd, Ni; L = C5H5, M = Ti; L = Me, n-Bu, M = Sn) Journal of Organometallic Chemistry, 385 (3). pp. 363-368. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(90)85007-L
Abstract
Treatment of a THF solution of (μ2-Te2)Fe2(CO)6 with LiEt3BH at −78°C gives the dianion [(μ-Te)2Fe2(CO)6]2-. The dianion reacts with the metal dihalides (PPh3)2MCl2, M = Pt, Pd, Ni, to give the neutral compounds (CO)6Fe2(μ3-Te)2M(PPh3)2, with Cp2TiCl2 to give (CO)6Fe2(μ3-Te)2TiCp2, or with R2SnCl2, R = Me, n-Bu to give (CO)6Fe2(μ3-Te)2SnR2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83041 |
| Deposited On: | 16 Feb 2012 04:18 |
| Last Modified: | 16 Feb 2012 04:18 |
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