Determination of interfacial dielectric constant of AOT-based reverse micelle by probing magnetic field effect on pyrene-DMA exciplex luminescence

Parui, Partha Pratim ; Nath, Deb Narayan ; Chowdhury, Mihir (2004) Determination of interfacial dielectric constant of AOT-based reverse micelle by probing magnetic field effect on pyrene-DMA exciplex luminescence Chemical Physics Letters, 396 (4-6). pp. 329-334. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...

Related URL: http://dx.doi.org/10.1016/j.cplett.2004.08.052

Abstract

The effect of magnetic field on the luminescence of pyrene-DMA exciplex confined within the reverse micellar (RM) environment of various cavity sizes is reported. The field-modulated change in luminescence Δφ/φ) at various w values is strikingly similar to the Δφ/φ vs dielectric constant (ε) variation of solvent mixtures which suggests that e of the RM interface is primarily responsible for the variation of magnetic field effect (MFE). The interfacial dielectric constant at different w values may be evaluated on the basis of the above similarity.

Item Type:Article
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ID Code:8304
Deposited On:26 Oct 2010 11:49
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