Mathur, Pradeep ; Avasare, Vidya D. ; Ghosh, Abhijit K. ; Mobin, Shaikh M. (2004) Formation of 5-phenyl-1,2-dithiole-3-thione from molybdenum dithiopropiolato complexes Journal of Organometallic Chemistry, 689 (7). pp. 1325-1327. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2004.01.022
Abstract
Molybdenum dithiopropiolato complexes, [(η5-C5R4R')Mo(CO)2(η2-S2CC≡CPh)] (R=H, R'=Me 1a, R=R'=H; 1b; R=R'=Me) react with trimethylamine-N-oxide (TMNO·2H2O) under mild thermolysis to form 5-phenyl-1,2-dithiole-3-thione (2). The reaction proceeds through the formation of the oxo-complexes, [(η5-C5R4R')Mo(O)(η3-S2CC≡CPh)] (R=H, R'=Me 3a, R=R'=H 3b; R=R'=Me). Direct reaction of 3a-c with TMNO · 2H2O under thermolysis also results in formation 2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Dithiolethione; Molybdenum; Dithiopropiolato; Carbonyl; Oxo |
| ID Code: | 83024 |
| Deposited On: | 16 Feb 2012 04:22 |
| Last Modified: | 16 Feb 2012 04:22 |
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